Electrolysis calculator: mass deposited and plating time

This electrolysis calculator follows OpenStax Chemistry: charge Q = I·t, moles of electrons n = Q/F, then moles and grams of metal. Example: 2 A for 60 minutes deposit 2.371 g of copper from a Cu²⁺ solution.

Example: Calculate: mass deposited · Metal (ion): copper Cu²⁺ (z = 2) · Current I 2 A · Time t 60 min → Result: Deposited mass 2.371 g. Source: OpenStax Chemistry 2e, 17.7 Electrolysis: Q = I·t and Q = n·F; Example 17.9 10.23 A for 1 h → 36,830 C → 0.3817 mol e⁻ → 41.19 g Ag; Al³⁺ 25.0 A, 15.0 min → 2.10 g Al; Example 17.10 chromium plating 33.46 A → 11.0 h (read 10.10.2026). Updated: .

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Result

Result
Deposited mass 2.371 g
Step by step
StepValue
MetalM = 63.546 g/mol, z = 2
Current I2 A
Time t60 min = 3,600 s
Charge QQ = I · t = 7,200 C
Moles of electrons n = Q/F7,200 C ÷ 96,485.33 C/mol = 0.0746 mol e⁻
Moles of metal0.0746 mol ÷ 2 = 0.0373 mol
Mass0.0373 mol × 63.546 g/mol = 2.371 g
Calculated for 100 % current efficiency: the whole charge deposits the chosen metal. If part of it drives other reactions, less metal is deposited.

How it is calculated

Faraday’s law in three steps: Q = I·t, n(e⁻) = Q/F, n(metal) = n(e⁻)/z. OpenStax Chemistry explains it like this: the current I (ampere = coulomb per second) multiplied by the time gives the charge Q; dividing by the Faraday constant F = 96,485.33 C/mol gives the moles of electrons; the half-reaction tells how many electrons z one ion needs. Multiply by the molar mass and you have the mass: m = I·t·M / (z·F).

Examples from OpenStax

ProcessDataResult
Silver plating, Ag⁺ + e⁻10.23 A, 1 h36,828 C → 0.3817 mol e⁻ → 41.17 g Ag
Aluminium, Al³⁺ + 3e⁻25.0 A, 15.0 min0.0777 mol → 2.10 g Al
Chromium plating, Cr³⁺ + 3e⁻237 g Cr, 33.46 A10.95 h
Copper, Cu²⁺ + 2e⁻2 A, 60 min2.371 g Cu

OpenStax gets 41.19 g of silver because it rounds to 36,830 C and 107.9 g/mol; with the CIAAW atomic weight 107.87 g/mol the calculator shows 41.17 g. For the chromium layer the book rounds to 11.0 h. The charge numbers z come from the half-reactions in OpenStax Appendix L: Ag⁺ needs one electron, Cu²⁺, Zn²⁺ and Ni²⁺ need two, Cr³⁺, Al³⁺ and Au³⁺ three. Gold can also be deposited from Au⁺ (z = 1) – then choose “enter molar mass and z”.

Time for a given mass

Turn the formula around: t = m·z·F / (M·I). Twice the current halves the time; a metal with z = 2 needs twice the charge of one with z = 1 for the same number of atoms. Molar masses of other substances come from the molar mass calculator; the cell voltage under non-standard conditions is calculated with the Nernst equation calculator.

Frequently asked questions

What is the formula for mass deposited in electrolysis?

m = I·t·M / (z·F): current times time gives the charge, divided by F = 96,485.33 C/mol and by z gives the moles of metal, times M gives grams.

How much copper do 2 A deposit in one hour?

About 2.371 g: 7,200 C ÷ 96,485.33 C/mol = 0.0746 mol e⁻, halved for Cu²⁺ = 0.0373 mol, times 63.546 g/mol.

What is the Faraday constant?

The charge of one mole of electrons: 96,485.332 12 C/mol, an exact value according to NIST CODATA.

How long does it take to deposit 237 g of chromium at 33.46 A?

About 10.95 hours (OpenStax rounds to 11.0 h): 4.558 mol Cr × 3 electrons × F = 1.32 × 10⁶ C.

Why is my real mass smaller?

The calculation assumes that the whole charge deposits the metal. Any charge used by other electrode reactions is missing from the metal.

What does z mean?

The number of electrons one ion takes up: 1 for Ag⁺, 2 for Cu²⁺, 3 for Al³⁺. It comes from the half-reaction.

Sources and legal basis

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